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SERUM ALUMINIUM LEVELS IN EGYPTIAN PATIENTS WITH

ALZHEIMER'S DISEASE">
     
 

SERUM ALUMINIUM LEVELS IN EGYPTIAN PATIENTS WITH

ALZHEIMER'S DISEASE,OTHER DEMENTIAS AND NORMAL AGING

A case-control study

George El-Nimr MB MRCPsych

Specialist Registrar in Old age Psychiatry, Manchester (formerly Resident in Neuropsychiatry, Alexandria University Hospital, Egypt)

* Emad Salib MB MSc MRCPI FRCPsych

Honorary Senior Lecturer, Liverpool University

Consultant Psychiatrist, Hollins Park Hospital Warrington

 Background:

In this study, serum aluminium in Egyptian patients with clinically diagnosed Alzheimer's disease, other dementias and non dementing controls of similar age and sex, was examined to see whether there is any significant difference between the three groups and between dementia syndrome as a whole and normal aging.

Method:    

Unmatched case - control study conducted at Alexandria University Hospital, comparing patients with a clinical diagnosis of Alzheimer's disease (NINCDS-ADRDA diagnostic criteria) and two control groups, in respect of their serum aluminium levels using Atomic Absorption Spectrophotometry.

Results:

There was a statistically significant difference between serum aluminium levels in Alzheimer's disease and other dementias and non dementing controls (P<.05).   No difference was found between serum aluminium levels in other dementias and non dementing controls.  Serum aluminium levels and the age distribution among patients with Alzheimer's disease showed a statistically significant positive correlation. 

Conclusion:

The study finding of a significant increase in the serum aluminium level in patients with Alzheimer's disease supports the hypothesis that aluminium may be implicated in Alzheimer's disease in some form.  Whether aluminium is an etiological factor in Alzheimer's disease or its presence is simply the result of age and changes in renal functions among Alzheimer's disease patients needs further assessment.   

KEY POINTS

Although available evidence for the role of aluminium in the pathogenesis of Alzheimer's disease over the last 36 years has remained largely circumstantial and unconfirmed, the aluminium hypothesis has not been rejected.

The statistically significant increase in the serum aluminium level among cases of Alzheimer's disease compared to other dementias and non dementing controls raises the question again about the role of aluminium as an etiological factor in the pathogenesis of Alzheimer's disease.

The small sample size, imposed mainly by the limited availability and cost of the Atomic Absorption Spectrophotometry, also the poor matching of the study groups are likely to reduce the study power and its inferential value.

Prospective studies are necessary to examine the incidence of Alzheimer's disease in high risk population exposed to neurotoxins such as aluminium.   A non-invasive, cost effective method to screen patients with Alzheimer's disease for clinical aluminium exposure and the risk of possible aluminium related cognitive changes may be the way forward.

Key words:

Alzheimer's disease

Aluminium hypothesis

Alzheimer's disease and aluminium

aluminium in dementia

Introduction:

Since early reports of the experimentally induced neurofibrillary degeneration1, a link between Alzheimer's disease and aluminium has been suspected. Although experimentally induced neurofibrillary degeneration provides some evidence for such link as, electron microscopy studies have shown that aluminium-induced tangles consist of bundles of normal neurofilaments which is in contrast with neurofibrillary tangles in Alzheimer's disease containing paired helical fibrils of abnormal tau protein2.   Epidemiological studies of exposure to aluminium  in drinking water3,4,5  have claimed a positive association between aluminium concentration in water and incidence of Alzheimer's disease.  Evidence that aluminium dust can be transported to the brain directly via nasal olfactory pathway6 suggests that the nasal olfactory route is another source of aluminium intake in occupational exposure.  Chronic exposure to aluminium and its possible neurotoxicity has been reported7 who showed that exposed miners were almost two times more cognitively impaired than the unexposed miners.   Salib & Hillier8 found no evidence to support any association between aluminium occupation and the risk of Alzheimer's disease later in life.   Broe et al9  Faltten et al10 found no increase in the incidence of Alzheimer's disease in high risk population such as patients consuming large amounts of aluminium containing antacids. However, serum aluminium was not checked in any of the  above studies. 

Although available evidence for the role of aluminium in the pathogenesis of Alzheimer's disease over the last 36 years has remained largely circumstantial and unconfirmed, the aluminium hypothesis has not been rejected11,12,13.

It is generally accepted that factors that govern the bioavailability, neurotoxicity and the effect of chronic low dose exposure to aluminium compounds, remain unclear11    

In this study, serum aluminium levels in patients with clinically diagnosed Alzheimer's disease, other dementias and a non dementing controls of similar age and sex, was examined to see whether there is any significant difference between the three groups and between dementia syndrome as a whole and normal aging.

Method:

An unmatched case - control study conducted at Alexandria University Hospital, comparing Egyptian patients with a clinical diagnosis of Alzheimer's disease and two control groups, in respect of their serum aluminium using Atomic Absorption Spectrophotometry.

Diagnostic criteria used in the study are those of:

NINCDS - ADRDA  'Alzheimer's disease and Related disorders Association - National institute of Neurological and Communicative Disorders and Stroke'14. The information needed to apply these criteria is obtained by standard methods of examination, medical history, Neurological and Psychiatric examination,  Neuro- psychological and laboratory studies.  Patients were assessed and assigned to one of three categories;

1) Alzheimer's disease (Group I): Probable or possible Alzheimer's disease (using NINCDS-ADRDA criteria)

2) Other dementias (Group II): Dementias other than Alzheimer's disease (with mini mental state examination15 < 17 and either a Hachiniski ischaemic score16 >7 or an identified other causes other than vascular. Patients who were receiving or known to have received dialysis were not included.

3) Non dementing controls (Group III) : No dementia (MMSE > 23).

All patients were selected from the Outpatient Clinics and Inpatient Units of Alexandria University Hospitals. The non dementing controls with similar age and sex, were selected from the same area of residence in Alexandria and its outskirts. 

The renal functions of all subjects was satisfactory. None of the patients were on dialysis nor were they on antacid medication.

Analytical procedure

Serum aluminium level was estimated by Atomic Absorption Spectrophotometry performed at the University Hospital Department of Biochemistry.

In the flameless type of Atomic Absorption Spectrophotometry, the sample is dispensed into a small graphic tube which can be heated electrically.  By increasing the temperature stepwise, the process of drying, thermal pre-treatment of the matrix and dissociation into free atoms (atomisation) can be separated.  During the drying and thermal pre-treatment stages, an inert pruge gas stream is passed through the tube to remove solvent and matrix vapours.  Blood samples were collected in the mornings as advised by the  Biochemistry Department of the Alexandra University Hospital, serum was separated and kept in the freezer till all samples were collected and ready for analysis.

Operating Parameters

Wave length:                            309 nm

Slit setting:                                0.7 nm

Lights source:                            Hollow cathode lamp

Tube/site:                                  Pyro/platform

Pre-treatment temperatures:       1700 c

Atomisation temperature:            2500 c

Techniques: Flameless

Analysis:           Analyze the sample versus the standard and reagent blank.

Calculations:     Serum aluminium ug/L: ug/mlx1000    Normal range:  <40 ug/L

Results:

The study sample included 44 patients categorised in the following groups:

Group I 

Alzheimer's disease                                           15 patients 

Group II

Multi-infarct dementia                                         6 patients 

Parkinson's dementia                                         4  patients

Miscellaneous (Pick's                                        4 patients

dementia, symptomatic dementia

and huntington's dementia)

Group III           

Non dementing controls from the                         15 subjects

same area of residence in Alexandria.         

Group I (Alzheimer's disease) had a mean level of 33.67 + 11.9 ug/L, ranging from 20 to 58 ug/L.   

In Group II (other dementias) mean aluminium level was 25.27 + 4.8 ug/L, ranging from 20 to 35 ug/L.   Group III (non dementing controls) had a mean level of 25.78 + 10 ug/L, ranging from 16 to 30 ug/L.  Table 1 summarises means of age and serum aluminium in the three groups.

Graph 1 illustrates mean serum levels in the study groups by Gender with significant difference between group means (ANOVA F 6.5 P<0.001  & Kruskal Wallis P<.05).    Using U-Mann Whitney and also t-test for 2 independent samples, there was statistically significant difference between serum aluminium levels Group I (Alzheimer's disease) and Group II (other dementias) and non dementing controls (P<.05).   No difference was found when comparing Group II (other dementias) and Group III (Control group) P=0.8.   Graph 2 shows a positive correlation between serum aluminium and age in the entire sample (r= 0.309  P=.07). Serum aluminium levels and the age distribution among patients with Alzheimer's disease showed that there was a statistically significant increase in the serum aluminium level with the progress of age for Alzheimer's disease group (Correlation co efficient r=0.5223  (P<.05) as in Graph 3, but not for other dementia or non dementing control group (r=0.03  P=0.8 and r=0.354  P=0.06 respectively).

The Difference between the distribution of serum aluminium Levels in patients with dementia as a whole (Group I & Group II combined) and those of the non dementing control group was found to be statistically significant (P<0.05) with higher mean in the dementia syndrome.  The difference was found in male and female patients.

Tables 2 & 3 show the significant difference between aetiological categories in respect of age and serum aluminium levels.  

Discussion:

1. Methodological limitations

1. The small sample size, imposed mainly by the limited availability and cost of the Atomic Absorption Spectrophotometry, also the poor matching of the study groups are likely to reduce the study power and its inferential value.

2.  A proportion of the Alzheimer's disease cases as well as controls are expected to have been incorrectly classified. It is possible that some Alzheimer's disease cases and other dementias may have had a combined aetiology. 

3. The patients with Alzheimer's disease that were admitted to the study may have differed  considerably from all incident or prevalent patients with Alzheimer's disease in respect of some attributes. 

4. Although the study groups came from a social environment with similar exposure opportunity, they may have been selected probably due to an advanced condition than those who were not referred to due to other medical or social problems.

5. It is possible that the increase in serum aluminium might have occurred at sometime before or even after the onset of cognitive decline.  There is also the possibility that serum aluminium may not accurately reflect brain aluminium. 

6. There was clear difference in age between the groups and also high standard deviation of age means within groups. Therefore, it is possible that the differences in serum aluminium levels between the study groups may have been attributed, at least partly, to the age difference rather than pathophysiology.

2. Interpretation of findings;

The statistically significant increase in the serum aluminium level among cases of Alzheimer's disease compared to other dementias and non dementing controls raises the question again about the role of aluminium as an etiological factor in the pathogenesis of Alzheimer's disease.    The findings are in keeping with 3 other studies; Kellet et al17 and Naylor et al18 reported significant increase in aluminium levels in the serum and whole blood of Alzheimer's disease patients.   Zapatero et al19 reported significant difference in serum aluminium in patients with Alzheimer's disease and age matched control group.  The difference was not statistically significant when cases with Alzheimer's disease were compared with dementias due to other causes which was not confirmed in our study. Zapatero et al19 also observed that serum aluminium increased with age which they attributed to enhanced gastric permeability or increased metal accumulation with age.

Shore et al20 and Pailler et al21, did not find elevated aluminium plasma levels in patient with Alzheimer's disease. serum,  CSF or hair in patients with Alzheimer's disease.  Also Mackenzie et al22  did not find any changes in serum aluminium in patients with epilepsy whose temporal lobectomies showed senile plaques lesions related to early stage of Alzheimer's disease.  The study finding of the significant increase in the serum aluminium level in Alzheimer's disease supports the hypothesis that aluminium may be implicated in Alzheimer's disease in some form,  and thus adds to the puzzle of "aluminium-Alzheimer link",  The increase in serum aluminium with age for whatever reason may suggest that aluminium compounds  should be limited in older people  because of the physiological accumulation of the metal during their life time19.  Whether aluminium is an etiological factor in Alzheimer's disease or its presence is simply the result of abnormal brain cellular metabolism among Alzheimer's disease patients needs further assessment23.    Although chronic exposure to aluminium is hypothesised to be a risk factor for the development of Alzheimer;s disease, it is unfortunate that the official values for aluminium in drinking water of the Egyptian regions where the sample members originated, were not available to add to the interpretation of findings.

However, findings of studies of exposure to aluminium  in drinking water3,4,5 which claimed positive association between aluminium concentration in water and incidence of Alzheimer's disease have not been conclusive.

Alzheimer's disease has no confirmed aetiology but there is strong evidence for the involvement of both genetic and environmental risk factors in its development. The interaction of hereditary and environmental factors such as aluminium in the aetiology of Alzheimer's disease is an area that future studies should pay special attention.   Prospective studies are necessary to examine the incidence of Alzheimer's disease in high risk population exposed to neurotoxins such as aluminium.   A non-invasive, cost effective method to screen patients with Alzheimer's disease for clinical aluminium exposure and the risk of possible aluminium related cognitive changes may be the way forward.

            "The possibility of a causal link between aluminium and Alzheimer's disease must be kept open until uncertainty about neuropathological evidence is resolved "

                                 Sir Richard Doll12 (1993)  

*Correspondence:

18 Broughton Close, Appleton, Warrington WA6 3DR

Tel: 01925 664123, Fax: 01925 664145

References:

1. Wisniewski,H. Klatzo I. (1965) Experimental production of neurofibrillary degeneration..Neuropathology and experimental neurology.1965; 27: 187- 199.

2. Munoz-Garcia (1986  An immunocytochemical comparison of cytoskeletal proteins in aluminium-induced and Alzheimer-type neurofibrillary tangles.

Acta Neuropathology Vol 70,pp 243-248

3. Martyn,C.N.;Barker,D. et al.(1989) Geographical relation between Alzheimer's disease and Aluminium in drinking water. The Lancet. No.8629,Jan 1989.p.59-62.

4. Michel, P. et al. (1990) Study of the relationship between aluminium concentration in drinking water and risk of Alzheimer's disease: IN Basic mechanism, Diagnosis and therapeutic strategies.  Iqbal K. John Wiley, Chichester91.

5. Neri, LC. (1991) Aluminium, Alzheimer's disease and drinking water.

The Lancet vol 338:August 10,1991.

6. Perl,D.P., Good, P. (1987) Uptake of aluminium into CNS along nasal Olfactory pathways.The Lance May 2, 1987.

7. Rifat,S. Eastwood  et al. (1990) Effect of exposure of miners to   aluminium powder.  The Lancet No. 8724 Nov1990 p. 59-62.

8. Salib E, Hillier (1996) A case-control study of Alzheimer's disease  and aluminium occupation   British Journal of Psychiatry 168(2) 244-9

9. Broe GA, Henderson AS, Creasey H et al (1990) A case-control study of Alzheimer's disease in Australia  Neurology Nov 1990; 40(11): 1698-707

10. Fallten TP., Glattre E., Viste A et al (1991) Mortality from dementia among gastroduodenal ulcer patients.  J Epidemiol nad Community health 45(3):203-206

11. Doll R. (1993) Review: Alzheimer's disease and environmental aluminium.  Age & ageing 1993; 22: 138-53.

12. Rifat,S. Aluminium hypothesis lives.  The Lancet Vol 343 Jan 94

13. Salib E (1989) Alzheimer's disease and the aluminium connection: A literature review

Int J of Psychiatry in Clinical Practice Vol 2 pp 181-188

14. Mckhann,G.;Drachman,D et al. (1984) Clinical diagnosis of Alzheimer's disease. Report of the NINCDS-ADADA, Task force on Alzheimer's disease. Neurology. 1984; 34: 939-944.

15. Folstein MF et al (1975) The mini mental state examination . A practical method for grading the cognitive state of patients for clinician 

J.Psych Res 1975,12:189-98.

16. Hachiniski VC et al(1975) . Cerebral blood flow in dementia.

Arch. Neurology. 32:632:637.

17. Kellet JM, Taylor A and Oram JJ (1989) Serum aluminium in Alzheimer's  disease  Lancet 1,682 (1986)

18. Naylor GJ, Smith AH, McHarg A (1989) Serum aluminium in Alzheimer's disease

Trace Elements Med 6, 93-95

19. Zapatero MD, Garcia DJ, Pascual F et al (1995) Serum aluminium levels in  Alzheimer's disease and other senile dementia   Biological Trace elements Research Vol 47 235-240

20. Shore D., Wyatt RJ (1983) Aluminium and Alzheimer's disease.

J of nervous and mental disease 171(9): 553-8

21.Pailler FM., Bequet D., Corbe H et al (1995) Aluminium. hypothetic cause of Alzheimer's disease.

Presse. Med 1995 Mar 11;24(10): 489-90.

22. Mackenzie IR., Mclachlan RS., Kubu CS et al (1996) Prospective neuropsychological assessment of nondemented patients with biopsy proven senile plaques. Neurology 1996; 46(2): 425-9

23. Mclachlan DR., Bergeron C., Smith JE et al (1996) Risk of neuropathologically confirmed Alzheimer's disease and residual aluminium in municipal drinking water employing weighted residential histories. Neurology 1996; 46(2):401-5

 

 

Table 1   Mean age and serum aluminium in the study groups

  

Mean age

Mean Aluminium (ug/L)

Group I

Alzheimer's disease

66.20 (sd 9.1)

range 55-88

 

33.67 sd 11.9

(20-58 ug/L)

Group II

Other dementias

63.60 (sd 11.2)

range 40-86

25.27 sd 4.8

(16-30 ug/L)

 

Group III

Non dementing

 

59.93 (sd 7.4)

range 45-70

25.78 sd 10

(20-35 ug/L)

 

 

Table 2

 

The significant differences in age between different groups with significance level: 0.05

MID

PD

MIS

Control

AD

Mean 66.2 years

Range 50=88 years

SD 9 years

<0.05

>0.05

<0.05

<0.05

MID

Mean 75.3 years

Range 60-86 years

SD 8.6 years

 

<0.05

<0.05

<0.05

PD

Mean 62.3 years

Range 55-67 years

SD 5.3 years

 

 

>0.05

>0.05

MIS

53 years

Range 40-67 years

SD 11.7 years

 

 

 

>0.05

AD: Alzheimer's disease       

MID: Multi infarct dementia

PD: Dementia in Parkinsons disease

MIS: Miscellaneous

* controls  Mean 59.9 years

            Range 45-70

            SD 7.4 years

 

Table 3

 

The significant differences in serum aluminium between different groups with significance level: 0.05

 

MID

PD

MIS

* Control

AD

Mean  33.6 ug/L

Range 20-58 ug/L

SD    11.86 ug/L

<0.05

>0.05

>0.05

<0.05

MID

Mean  24.8 ug/L

Range 20-32 ug/L

SD    4.4 ug/L   

 

>0.05

>0.05

>0.05

PD

Mean  26 ug/L

Range 21-30g/L

SD    3.9 ug/L   

 

 

>0.05

>0.05

MIS

Mean  32.8 ug/L

Range 20-51 ug/L

SD    12 ug/L

 

 

 

>0.05

 AD: Alzheimer's disease       

MID: Multi infarct dementia

PD: Dementia in Parkinsons disease

MIS: Miscellaneous

* Controls Mean 25.5 ug/L

           Range 16-30 yg/L

           SD 4.8 ug/L

 
     

 

 
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